Preheat the air fryer to 390°F.
Pat the shrimp dry and place in a bowl. Add olive oil, garlic powder, paprika, onion powder, salt, and black pepper. Toss well to coat.
In a separate bowl, toss the broccoli and sliced bell pepper with olive oil, salt, and black pepper.
Add the broccoli and bell pepper to the air fryer basket in a single layer. Air fry for 8 to 10 minutes, shaking halfway, until tender and lightly crisp.
Remove the vegetables and set aside.
Place the shrimp in the air fryer basket in a single layer. Air fry for 6 to 8 minutes, shaking halfway, until the shrimp are pink and cooked through.
Divide the rice, vegetables, and shrimp evenly into meal prep containers.
Let cool slightly, then cover and store in the refrigerator.